yes, you will want to read up on it and ask lots of questions so you know what you are doing.
besides looking here in the DIY finishing section you might want to check out
http://www.reranch.com/basics.htm
http://www.stewmac.com/shop/Video,_DVD/Finishing,_repair/Spray_Finishing_Videos.html
http://www.stewmac.com/shop/Books,_plans/Building_and_repair:_Finishing/Guitar_Finishing_Step-By-Step.html
Brian