Just for fun,
here's a site that explains what happens when you connect capacitors in series or parallel.
The general rule of thumb if you don't want to do much math is: caps in parallel add, and caps in series divide. The adding part is easy and straightforward - just add up all the values any you're there. The dividing part is a little more complex, but just keep in mind the total capacitance is going to be lower than the smallest value.
I've found over the years that with most pickups a .022µF is ideal for just about any guitar. Anything more than that tends to roll off so much high end that it gets into the mids and starts to make the tone control behave like a defective volume control. Anything lower, and it has too little effect. Either way, you seem to be reaching for unusable areas, which I suspect is why many folks don't use their tone controls. Throw a .01µF cap in, and it does nearly nothing while with a .047µF cap in there you can hardly touch the control without losing a ton of signal.
There are those that
like a radical range, and for them I'd say put a .01µF and .022µF in parallel to get a .033µF. Roughly. But, that's as far as I'd go. Caps and resistors are usually pretty sloppy, tolerance-wise, so figure within 20% of those values. Which is, incidentally, why some folks think some caps sound different. They don't. They don't have a sound, they have a reactance, which is based on capacitance. So, an expensive .022µF oil-over-paper may sound different than a cheap .022µF ceramic, but that's only because neither one of them is actually a .022µF cap. They'll both be marked that way, but one may be a .019µF part while the other is a .024µF part.