Everything about all the finishes <long read, sourced>

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-CB-

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Source: http://www.taunton.com/finewoodworking/pages/w00060.asp

Finishing is one of the biggest bugaboos for many woodworkers. Though they remain undaunted by complex joinery or intricate and precise machining, scores of woodworkers still cringe at the thought of applying a finish to their work. "What's the best finish for my project?" is a question I often hear. Being able to answer that question confidently and comfortably is an important hurdle to overcome.

Finishing products can be grouped into manageable categories, based on general working qualities and the degrees of protection they offer: waxes, oils, varnishes, shellacs, lacquers and water-based finishes. Different finishes offer varying degrees of protection, durability, ease of application, repairability and aesthetics. Unfortunately, no single finish excels in all of these categories -- a finish that excels in one may fail in another -- so in choosing a finish you must accept trade-offs.

As a professional refinisher, I routinely ask my customers a series of questions to determine the best finish for their furniture. I've modified my standard questions for this article and added a few as a Checklist for woodworkers trying to decide which finish to use on their own projects. Answers to these questions will point you toward the right finish to use on a given project, based on how well you need to protect the surface, how well the finish will hold up, how easy it is to apply and how you want it to look. To get a better understanding of the choices, let's first take a look at the different categories of wood finishes.

An overview of what's out there:
All wood finishes can be classified as one of two distinctly different types, based on how they dry, or cure. Evaporative finishes--such as lacquer, shellac and many water-based finishes--dry to a hard film as the solvents evaporate. (Water is not a solvent -- it's a carrier for the finish emulsion.) These types of finishes will always redissolve in the solvent used to thin them, long after they've dried, so they tend to be less durable than reactive finishes. Most reactive finishes -- such as linseed or tung oil, catalyzed lacquers and varnishes -- also contain solvents that evaporate, but they cure by reacting with either air outside the can or a chemical placed in the can before application. These finishes undergo a chemical change as they cure, and after that they will not redissolve in the solvent originally used to thin them. Except for the pure oils, reactive finishes tend to hold up better to heat and chemicals. See Common finish products compared for a summary of how the finishes stack up against each other.

Waxes -- I don't consider wax an appropriate finish in and of itself. I use paste wax (carnauba mostly, sometimes beeswax) to polish furniture but only over other finishes, such as lacquer or shellac.

The true oils -- Linseed oil and tung oil, the drying oils most often used in finishing, are readily available and relatively inexpensive. These finishes are called true oils to distinguish them from other products hyped as oil finishes and to separate them from naturally nondrying or semidrying oils used in finishes, such as soybean oil. These true oils change from a liquid to a solid through polymerization, a process that strengthens the cured finish.

Linseed oil is available in several forms. Unrefined, it's called raw linseed oil, which is rarely used on wood because it dries so slowly. Finishers long ago discovered that by boiling the oil, the resulting product was thicker and dried more quickly. Even though linseed oil that has actually been boiled is still available -- it's called heat-treated or polymerized oil -- most of the boiled linseed oil sold these days is raw oil that has been mixed with chemical additives to speed up the drying time. For wood finishing, you should use only boiled linseed oil.

Tung oil is derived from the nuts of trees that are native to Asia but have been cultivated in other parts of the world. Tung oil is available in a pure, unrefined form and in a heat-treated or polymerized form. The heat-treating process makes the oil a bit more durable and speeds up the drying time. It also minimizes a tendency of tung oil to "frost" (dry to a whitish, matte appearance). Tung oil is paler in color and has better moisture resistance than linseed oil.

Both linseed and tung oils are penetrating finishes, which means they penetrate the fibers of the wood and harden. These are the easiest finishes to apply: Wipe them on, allow them to penetrate the surface of the wood and wipe off the excess with a rag. These oils are usually not built up with enough coats to form a surface film, like that of varnish or lacquer, because the film is too soft.

Varnishes -- Varnish is made of tough and durable synthetic resins that have been modified with drying oils. Labels on cans of varnish will list resins such as alkyd, phenolic and urethane, and the oils used are tung and linseed, as well as other semidrying oils such as soybean and safflower. Varnish cures by the same process as true oils -- polymerization -- but the resins make this finish more durable than oil. In fact, oil-based varnish is the most durable finish that can be easily applied by the average woodworker. Varnish surpasses most other finishes in its resistance to water, heat, solvents and other chemicals.

Varnishes that contain a high percentage of oil are called long-oil varnishes. These include marine, spar or exterior varnishes and some interior varnishes for sale on the retail market. Long-oil varnishes are more elastic and softer than medium- and short-oil varnishes that contain a lower percentage of oil. Medium-oil varnishes comprise most interior varnishes on the market. Short-oil varnishes (also known as heat-set varnishes and baking enamels) require extremely high temperatures to dry, so they're used only in industrial applications.

The type of resin used in the varnish determines the characteristics of the finish. Alkyd varnish is the standard all-purpose interior variety with decent protective qualities. Phenolic varnish, usually made with tung oil, is predominantly for exterior use. Urethane varnish, also called polyurethane, offers a better resistance to heat, solvents and abrasions than any other varnish.

Varnish is typically applied with a brush, although a highly thinned and gelled version, called wiping varnish, can be applied with a rag.

Oil and varnish blends -- These mixtures, mostly oil with some varnish added, offer some of the best attributes of both ingredients: the easy application of true oils and the protective qualities of varnish. (Watco-brand Danish oil, teak oil and a number of other finishes fall into this category.) It's difficult to ascribe accurate protective qualities to these products because manufacturers don't usually disclose the ratio of oil to varnish. Oil and varnish blends will dry a bit harder than true oils, and the finishes will build quicker with fewer applications.

Shellacs -- While most people think of shellac as a liquid finish found at a paint store, in its pure form it's a natural resin secreted from a bug that feeds on trees, mostly in India and Thailand. The secretions, in the form of cocoons, are gathered and eventually refined into dry flakes, which are then dissolved in denatured (ethyl) alcohol to make the shellac solution that winds up in cans at the store.

Shellac is available in several varieties. You can buy it premixed, or you can buy it in flake form and mix it yourself with denatured alcohol. The premixed variety is available in orange (amber) and clear, which is shellac that's been bleached. With the flakes, shellac is available in a wider variety of colors and wax contents than with the premixed version (which contains wax). The wax in shellac decreases the finish's resistance to water and prevents some finishes from bonding to it.

Lacquers -- Most professionals still regard lacquer as the best all-around finish for wood because it dries fast, imparts an incredible depth and richness to the wood, exhibits moderate to excellent durability (depending on the type used) and rubs out well. There are several different types of lacquer, and they exhibit different performance characteristics.

Nitrocellulose lacquer is the most common. If the label on the can says lacquer, it's most likely nitrocellulose, which is made from an alkyd and nitrocellulose resin dissolved and then mixed with solvents that evaporate quickly. This type of lacquer has moderate water resistance, but it's sensitive to heat and certain solvents. The biggest drawback is the finish's tendency to yellow as it ages, which shows clearly on light-colored woods.

Acrylic-modified lacquer is made from a mixture of a nonyellowing cellulose resin (called cellulose acetate butyrate, or CAB) and acrylic. This lacquer possesses the same general properties of nitrocellulose lacquer, except it is absolutely water-white, meaning it will not show as an amber color when applied over light-colored woods. Also, the finish won't turn yellow over time.

Catalyzed lacquer bridges the gap between the application traits of nitrocellulose lacquer and the durability of varnish. Catalyzed lacquer is a complex finish composed of urea formaldehyde or urea melamine and an alkyd that has some nitrocellulose resin added to make it handle like normal lacquer. The addition of an acid catalyst initiates a chemical reaction that forms a very tough, durable finish. Catalyzed lacquer comes in two versions: precatalyzed and post-catalyzed. Precatalyzed lacquer has the components premixed, either by the manufacturer or at the store when you buy it; post-catalyzed lacquer is a two-part system that you must mix in your shop, following precise ratios. Once the catalyst has been added, these lacquers have a fairly short pot life (the time in which they can be used).

Water-based finishes -- Water-based finish contains some of the same ingredients as varnish and lacquer -- notably urethane, alkyd and acrylic -- but many flammable and polluting ingredients have been replaced with water. The chemistry in this product is complex. Because the resins don't have a natural affinity for water, they must be chemically modified or forced to combine with water.

Water-based finish is usually made with either an acrylic resin (sold as water-based lacquer) or an acrylic urethane mixture (sold as water-based polyurethane). As with varnish, the addition of the urethane makes the resin tougher and more scratch resistant, but water-based urethane does not have the same solvent and heat resistance as its oil-based counterpart.

What finishes are more durable?
The durability of a finish is measured by its resistance to water, chemicals, solvents (such as those in alkaline cleaners and acidic foods), heat and scratches. Wax, shellac, lacquer and some water-based finishes will be damaged if exposed to water long enough. Most of these products also scratch easily; however, they rub out well. (That's the flip side of scratch resistance.) Wax is surprisingly resistant to acids and alkalis. Aside from that, it is the least durable finish. Shellac is neither resistant to alkalis such as ammonia nor to alcohol. Of all the evaporative finishes, lacquer (nitrocellulose and acrylic, water- and solvent-based) fare the best in terms of overall durability. Oil-based polyurethane is the most durable finish you can apply by hand, and catalyzed lacquer and varnish are the most durable sprayed finishes.

Choose a finish to match your skill level
Your level of experience, the environment in which you work and whether you're set up to spray all play a part in deciding which finish to use. The temperature and dampness of your shop, as well as the amount of sanding dust in the air, will affect your choice. Dust falling onto a finish does not pose as great a problem with lacquer or shellac as it would with a slow-drying finish such as varnish. Shellac and lacquer are also the least temperamental when it comes to cold temperatures, and they can be modified with retarder additives for hot and humid conditions. Oils and oil-based products dry slowly in cold temperatures and humid conditions, and dust is always a problem when it has time to become embedded in the dried film.

Spray equipment requires a larger budget and, in most cases, expensive equipment to exhaust the overspray. There's also a learning curve with spraying, so it will likely take some practice before you get decent results.

The type of finish will notably affect the look of the wood
Do you want a natural "in-the-wood" finish? Or does your work demand an elegant, deep, glass-smooth finish? Is the color of the finish a problem, or will yellowing of the finish be a problem down the road?

Traditionally, woodworkers have turned to oil, wax or oil and varnish blends (such as Watco) for a natural-looking finish. None of these easy-to-apply finishes dries to form a hard surface film. However, you can get a natural-looking effect with any finish -- including varnish, shellac and lacquer -- as long as you don't build it up more than a few coats and you rub out the dried film with steel wool. But if your goal is a filled-pore, deep, lustrous finish, you must use a hard, film-forming finish (varnish, shellac or lacquer). This type of finish is also mandatory when you have to perform complex coloring options like toning and glazing.

The color and the penetration of the finish itself may be an issue. Orange shellac and phenolic-resin varnish both have colors that may be too dark for woods that you may want to keep as light as possible. In addition, many finishes deepen or darken the wood surface. In most cases this is desirable, because it adds depth and increases luster. However, you may want to downplay any deepening effect. Some delicately figured woods (such as pearwood) will appear muddy when an oil finish is applied.

Oil and oil-based varnish, solvent-based lacquer and shellac all deepen the color of the wood and increase surface luster the most. These finishes wet the cells of the wood, penetrating into the surface. Other film finishes -- notably water-based finishes and some catalyzed lacquers -- tend to lie on the surface. By not penetrating it as much, they make the wood appear lighter in color.

The plastic look that's sometimes ascribed to polyurethane and catalyzed lacquers has more to do with the incorrect application of these finishes than it does with the finishes themselves. On open-pored woods (plainsawn ash or oak, for example) the application of thick varnish and lacquer can result in a soupy look on the surface. This is a consequence of the finish film bridging across the open pores rather than flowing into them. By thinning these finishes you can achieve more attractive results. My favorite method to apply oil-based polyurethane is to thin the finish 50% with mineral spirits and wipe it on.

A finish film that turns yellow with age will be noticeable with unstained, light-colored woods, such as maple or birch. An acrylic finish, water- or solvent-based, does not have this problem. Paste wax and some catalyzed finishes also will not yellow.

Think about safety and the environment
A solvent-based finish, such as varnish and lacquer, contains a good deal of organic solvents, which can affect the environment as well as your health. It's also highly flammable. If these particulars pose a problem for you, use a water-based finish to eliminate the fire hazard and to mitigate the environmental and health impact. Pure oil is a surprisingly good alternative to a solvent-based lacquer or varnish: Pure oil contains no solvents and comes from renewable resources. However, oil-soaked rags must be disposed of carefully. Shellac is also a good alternative. The solvent for shellac, denatured alcohol, is distilled from corn, and most people don't find the fleeting odor objectionable.

All finishes are nontoxic when fully cured, despite what you may have read or heard. Once the solvents have evaporated, any cured film is safe for contact with food. This does not mean that the finish itself is safe to gobble up. It means simply that additives such as heavy-metal driers and plasticizers are encapsulated well enough that they do not migrate into your food. Wax and shellac (apples and candy are coated with these) are the only edible finishes that I'm aware of, besides mineral oil, which is sold as a laxative.

Spraying wastes a great deal of the finish material, and the organic solvents are dispersed into the air. Brushing or wiping on a finish is a practical, though less speedy, alternative.

Jeff Jewitt writes frequently for Fine Woodworking. His latest book, Great Wood Finishes, was recently published by The Taunton Press.


= CB's note, TrueOil is not a true oil, but an oil-varnish mix, as described in the excellent text above.
 
Right friggin on -CB-,  we all needed that!  I'm going to go read it three or four more times.
 
THANKS CB!  You've probably just saved yourself a lot of time explaining this stuff over and over.  You are the man.
 
Put a "sticky" on that one, as it answers half the questions that get posted to DIY Finishing....
 
Source:  http://www.turnwood.net/projects/amazingCAGluefinish_BHaskell.html

Amazing Finish
By Bill Haskell
written for American Woodturner Magazine

    Here is an approach to putting a finish on your turned work, believe it or not, that uses a glue to achieve striking results. The glue is cyanoacrylate and it comes in various forms and brand names. The chemical abbreviation for cyanoacrylate is CA, which the glue is often called. Hot Stuff is a popular brand of CA glue used by woodworkers. Sometimes, a person who has never heard of CA glue or Hot Stuff can relate to the name Super Glue or Krazy Glue. These are common household CA glue brands and there is even a version sold to repair broken fingernails.

There is a host of ways that CA glue can be used beneficially in woodturning; I always have some on hand. Examples of what it can be used for are filling and repairing cracks, voids and knots; gluing turning blocks to scrap blocks on a faceplate for immediate use; and reinforcing the bond of bark to sap wood on natural edges, just to name a few.

Most who know of and use CA glue as a quick reacting adhesive, are amazed, and even find it hard to believe, that this glue can be used as a wood finish. Well, it can, and it gives a very hard and remarkably protective surface that works well in certain applications.

You may be even more astonished to know that CA glue is used in surgery and on battlefield to mend and adhere human flesh to stop bleeding.

In using CA glue for a woodworking finish, there are obvious and some not so obvious characteristics that are inherent to this technique. Here is a synopsis of the pros and cons:

Advantages:
• Very hard finish
• Gives added strength for turning thin and fragile walls, especially with voids, knots, etc.
• Stabilizes punky and soft wood
• Provides sharper color and figure definition than most finishes
• Does not yellow over time or give a muddy appearance like oil based finishes
• Needs no maintenance over the years; e.g. waxing, polishing, etc.
• Does not require a lot of coats for build-up

Disadvantages:
• Can be tricky to learn how to use
• Fumes from the liquid glue can be irritating
• Can not be applied with brush or sprayed
• When polished it has a high gloss finish that some find unappealing
• Relatively expensive
• More time consuming to apply than a one or two coat finish, but not more than a multiple coat rubbed out finish
• Easy to sand or polish through the surface to bare wood

I started using a CA finish on California buckeye burl hollow forms. Buckeye burl often has bark inclusions that make vessel walls fragile, and the wood is soft. I use CA on the outside of a hollow form to give it strength while turning the inside wall thin. A demonstration given by J. Paul Finnell a number of years ago introduced me to this technique. Paul turned eggshell thin walls, and the CA gave him a measure of support that allowed him to turn down to a wall thickness of 1/8” or thinner. I found that when additional coats were applied and the surface sanded and polished, the swirling colors and patterns of the buckeye burl were clearer and more dramatic than I had ever seen before. Yes, the high gloss seemed artificial, but the spectacular color and detail were so attractive, I found I could live with the sheen. Come to think of it, I have seen a beautiful finish with a similar appearance on expensive hardwood car dashboards.

To compare the results, I took a piece of buckeye burl and applied CA glue to one-half and lacquer to the other half. Both were rubbed out and polished after a good build up. Side by side, the difference between the two types of finishes can be seen, especially the greater color fidelity and detail sharpness of the CA finish. Some will like the CA finish, others will not. It’s a matter of personal preference.

I talked to the manager of the Hot Stuff Company, and I learned that he had used CA glue as a finish. However, he was familiar with finishing flat surfaces, not round. For example, he had finished a breakfast room tabletop with CA glue and achieved a harder and more moisture resistant surface, he claimed, than could be accomplished with a bar top varnish or boat spar varnish. As another example, he also mentioned how a customer that makes custom guitars sometimes uses CA glue coating on guitar backs to create a different but desired sound. These are just a few examples of how CA glue can be used to treat the surface of wood for a reason other than gluing or repairing.

The method I use to apply CA glue as a finish for turned pieces is outlined below. Recognize that this is my approach, the one that works for me. Other turners may find that variations to this method will work as well or better for them. It’s a tricky finish to apply and achieve the desired results, but it can be well worth the effort and the learning process to get there.

CA Glue Finish Procedure

Turning:

1. I typically apply this kind of finish only to the outside of a hollow vessel with a small opening. Bowl forms are a little more difficult to do on the inside, depending on the degree of enclosure, when sanding and buffing the inside finish. I will address only an outside application here; the same methods can be used to do the inside of a bowl.

2. Complete all turning and sanding to final grit.

3. In my hollow vessel process, the vessel foot and neck are left oversized for strength and support. These areas are not turned to final form until all hollowing is complete.

Application:

1. Mounted on the lathe, before turning the inside of a hollow vessel, apply a coat of thin viscosity CA glue to the outside surface. I used to use the medium viscosity glue, but now I prefer the thin version and apply only a penetrating sealer coat.

2. Apply by pouring a few drops on the piece and spread with a finger covered with latex glove or finger cot. I’m told Rude Olsonik would put this finish on with his bare finger, and after a number of applications and build up, he would peel the coating off. I have not found that it peels off easily; however, I didn’t let a number of coats build up either.

3. Cover several square inches with each application and repeat until the entire surface is coated. Spread on quickly and as smoothly as possible. Do not go over an area again once the glue starts to set up.

4. Fully coat the piece and let the glue cure and set up. Depending on the moisture and chemical content in the wood and other conditions, it may take anywhere from several minutes to 30 minutes to set up. I try to be patient (difficult) and wait for natural curing. Using an accelerator works, but may make the cured glue more brittle.

Sanding:

1. The CA glue will set up with a rough surface, so it must be sanded smooth. Briefly sand the piece with the lathe on at a low speed using 220 grit paper. After the high spots have been sanded, stop the lathe and sand the remaining high spots, bumps, etc. by hand with the lathe stopped. This will take a few minutes and some patience. Finish sanding with 320 grit paper.

2. In the sanding process, take care to sand as little as possible while getting down to a completely smooth and fully sanded surface. Good lighting will expose shinny areas or dimples, which require more sanding. Beware, too much sanding will go through the surface and expose bare wood.

3. At this point, one must decide on what kind of final finish is desired; there are two alternatives:

a. Put another coat or two of CA glue on in the same manner, or

b. Apply spray lacquer or other finishes when the piece is completely done.

c. I used to do the former, but now prefer applying spray lacquer to a base sealer CA coat. This is much easier and less risky. With two or three coats of CA, sanding and polishing often created a bare spot or two. These are difficult to repair without creating more bare spots.

d. With the base CA sealer coat, the color and fidelity of the wood color and figure has been preserved, and then the lacquer applied over the CA gives a fine deep protective coating.

Polishing:

1. After the CA finish has been sanded smooth, down to 320 or 400 grit, rub out with 00 steel wool. You are now ready to polish on a buffing wheel.

2. Buff with a soft cotton wheel no faster than 1750 RPM, using a compound like white diamond. Tripoli is too coursing. Be careful when buffing - you want to remove the scratches, but it is very easy to buff right through the CA finish to the bare wood.

3. This is not a problem if lacquer is going to be applied over the CA base coat. However, if CA is going to be the only finish, repair by wiping CA glue on the spot, sand, and polish. Making these repairs runs the risk of creating more bare wood spots, so be as careful as possible to keep from going through the CA finish.

4. After polishing is complete, I have tried to reduce the sheen by rubbing with 0000 steel wool, pumice, or rottenstone, but have not liked the results.

Conclusion:

1. This total procedure takes practice and patience to accomplish well. It is a good idea to practice on a turned scrap piece until you get the hang of it. After you feel comfortable with the procedure, try it on a better-turned piece. Good Luck!

2. This finish works best on woods with pattern and color variation (California buckeye, Paralam, burls, spalted wood, etc.). Unavoidable imperfections in the cured CA will be more visible on plain wood like maple or walnut.

3. No doubt, there are other applications where this finish will prove beneficial. I know of some turners who have used it for pens because of its hard finish.

4. This procedure may sound complicated and difficult, but once it is learned and used, it’s not any more difficult than other finishes that achieve stupendous results.
 
Great information, thank you very much. Any opinions on how the different finishes might effect the sound of a body? Some people seem to think oil finishes deaden and things like Nitro lacquer livens the sound, any info on that would be greatly appreciated.
 
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